姓名：黄跟平

职称：教授，博导

专业：有机化学、计算化学

办公室：北洋园校区51教学楼432室

实验室：北洋园校区51教学楼443室

EMAIL：gphuang@tju.edu.cn

微信：hgp-1984

课题组主页：https://www.x-mol.com/groups/gphuang；http://tj.teacher.360eol.com/teacherBasic/preview?teacherId=2950

一、学习与工作简历：

2020.07-至今：天津大学化学系（教授）

2014.12-2020.06：天津大学化学系（副教授）

2011.08-2014.12：瑞典斯德哥尔摩大学（博士后，Fahmi Himo教授课题组）

2009.09-2011.03：温州大学（访问研究生，夏远志教授课题组）

2006.09-2011.07：中国科学院青海盐湖研究所（博士，李亚红教授课题组）

2002.09-2006.07：合肥工业大学（学士）

二、研究方向：

课题组主要使用商用量化软件Gaussian对有机化学和金属有机化学反应进行理论计算研究，通过对实验中难以观察到的中间体和过渡态的结构优化和能量计算，在分子水平层面上理解化学反应，在确定反应机理的基础之上探讨调控反应活性和选择性的规律，并进一步预测设计新的反应体系以及使用实验手段加以验证。

三、指导研究生情况：（每年计划招收研究生2名，有兴趣的同学可以直接邮件咨询）

四、主要研究成果（共发表论文40余篇，详细列表请访问课题组主页）：

1. L. Hu, A. Cai, Z. Wu, A. W. Kleij*, G. Huang*. A Mechanistic Analysis of the Pd-Catalyzed Formation of Branched Allylic Amines reveals the Origin of the Regio- and Enantioselectivity through a Unique Inner-Sphere Pathway.Angew. Chem. Int. Ed.2019,58,14694.

2. G. Huang, M. Kalek, F. Himo*. Mechanism and Selectivity of Rhodium-Catalyzed 1:2 Coupling of Aldehydes and Allenes.J. Am. Chem. Soc.2013,135, 7647.

3. G. Huang*, P. Liu*. Mechanism and Origins of Ligand-Controlled Linear versus Branched Selectivity of Iridium-Catalyzed Hydroarylation of Alkenes.ACS Catal.2016,6, 809.

4. G. Huang, Y. Xia*. Catalyst-Controlled C-C σ Bond Cleavages in Metal Halide-Catalyzed Cycloisomerization of 3-Acylcyclopropenes via a Formal 1,1-Halometalation Mechanism: Insights from Quantum Chemical Calculations.ACS Catal.2015,5,859.

5. G. Huang, M. Kalek, R.-Z. Liao, F. Himo*. Mechanism, Reactivity, and Selectivity of Iridium-Catalyzed C(sp3)-H Borylation of Chlorosilanes.Chem. Sci.2015,6, 1735.

6. X. Li, X. Ren, H. Wu, W. Zhao, X. Tang*, G. Huang*. Mechanism and Selectivity of Copper-Catalyzed Borocyanation of 1-Aryl-1,3-Butadienes: A Computational Study.Chin. Chem. Lett. 2021,32,9.

7. Z. Wu, M. Zhang, Y. Shi, G. Huang*. Mechanism and Origins of Stereo- and Enantioselectivities of Palladium-Catalyzed Hydroamination of Racemic Internal Allenes via Dynamic Kinetic Resolution: A Computational Study.Org. Chem. Front. 2020,7, 1502.

8. X. Li, H. Wu, Z. Wu,G. Huang*. Mechanism and Origins of Regioselectivity of Copper-Catalyzed Borocyanation of 2-Aryl-Substituted 1,3-Dienes: A Computational Study.J. Org. Chem. 2019,84, 5514.

9. M. Zhang, J. Liang,G. Huang*. Mechanism and Origins of Enantioselectivity of Iridium-Catalyzed Intramolecular Silylation of Unactivated C(sp3)-H Bonds.J. Org. Chem. 2019,84, 2372.

10. G. Liu*, F. Han, C. Liu, H. Wu, Y. Zeng, R. Zhu, X. Yu, S. Rao,G. Huang*, J. Wang*. A Highly Active Catalyst System for Suzuki-Miyaura Coupling of Aryl Chlorides.Organometallics. 2019,38, 1459.

11. M. R. Elsby, J. Liu, S. Zhu, L. Hu,G. Huang*, S. A. Johnson*. Influence of N-Heterocyclic Carbene Steric Bulk on Selectivity in Nickel Catalyzed C-H Bond Silylation, Germylation and Stannylation.Organometallics. 2019,38, 436.

12. H. Wu, X. Li, X. Tang,G. Huang*. Mechanism and Origins of Chemo- and Regioselectivities of (NHC)NiH-Catalyzed Cross-Hydroalkenylation of Vinyl Ethers with α-Olefins: A Computational Study.Org. Chem. Front. 2018,5, 3410.

13. L. Hu, Z. Wu,G. Huang*. Mechanism and Origins of Regio- and Stereoselectivities in Iridium-Catalyzed Isomerization of 1-Alkenes totrans-2-Alkenes.Org. Lett.2018,20, 5410.

14. H. Wu, X. Li, X. Tang, C. Feng*,G. Huang*. Mechanisms of Rhodium(III)-Catalyzed C-H Functionalizations of Benzamides with α,α-Difluoromethylene Alkynes.J. Org. Chem. 2018,83, 9220.

15. X. Li, H. Wu, Y. Lang,G. Huang*. Mechanism, Selectivity, and Reactivity of Iridium- and Rhodium-Catalyzed Intermolecular Ketone α-Alkylation with Unactivated Olefins via an Enamide Directing Strategy.Catal. Sci. Technol. 2018,8, 2417.

16. Y. Lang, M. Zhang, Y. Cao,G. Huang*. Mechanism and Origins of the Directing Group-ControlledEndo- VersusExo-Selectivity of Iridium-Catalysed Intramolecular Hydroalkenylation of 1,1-Disubstituted Alkenes.Chem. Commun. 2018,54, 2678.

17. M. Zhang, L. Hu, Y. Lang, Y. Cao,G. Huang*. Mechanism and Origins of Regio- and Enantioselectivities of Iridium-Catalyzed Hydroarylation of Alkenyl Ethers.J. Org. Chem. 2018,83, 2937.

18. H. Zou, Z.-L. Wang*, Y. Cao,G. Huang*. Mechanism of Rhodium(III)-Catalyzed Formal C(sp3)-H Activation/Spiroannulation of α-Arylidene Pyrazolones with Alkynes: A Computational Study.Chin. Chem. Lett. 2018,29, 1355.

19. G. Huang, C. Diner, K. J. Szabó*, F. Himo*. Mechanism and Stereoselectivity of BINOL-Catalyzed Allylboration of Skatoles.Org. Lett.2017,19, 5904.

20. J. Wu, D. Wang, X. Chen, Q. Gui, H. Li, Z. Tan*,G. Huang*, G. Wang*. Synthesis of 4-benzylpyridines via Pd-catalyzed CH3-arylation of 4-picoline.Org. Biomol. Chem.2017,15, 7509.

21. H. Zou, Z.-L. Wang,G. Huang*. Mechanism and Origins of Chemo- and Regioselectivities in Nickel-Catalyzed Intermolecular Cycloadditions of Benzocyclobutenones with 1,3-Dienes.Chem. Eur. J.2017,23, 12593.

22. L. Wang, H. Zou, X. Zhang,G. Huang*. Mechanism and Origins of Selectivity in Rhodium-Catalyzed Intermolecular [3+2] Cycloadditions of Vinylaziridines with Allenes.Org. Chem. Front.2017,4, 587.

23. M. Zhang,G. Huang*. Mechanism of Iridium-Catalysed Branched-Selective Hydroarylation of Vinyl Ethers: A Computational Study.Dalton Trans.2016,45, 3552.

24. M. Zhang,G. Huang*. Mechanism and Selectivity of Ru(II)- and Rh(III)-Catalyzed Oxidative Spiroannulation of Naphthols and Phenols with Alkynes via a C-H Activation/Dearomatization Strategy.Chem. Eur. J.2016,22, 9356.

25. X. Zhang, H. Zou,G. Huang*. Mechanism and Origins of Ligand-Controlled Selectivity of Rhodium-Catalyzed Intermolecular Cycloadditions of Vinylaziridines with Alkynes.ChemCatChem2016,8, 2459.

26. G. Huang*. Mechanism and Selectivity in Rhodium-Catalyzed [7+2] Cycloaddition and Cyclopropanation/Cyclization of Allenylcyclopentane-alkynes: Metallacycle-Directed C(sp3)-C(sp3) vs C(sp3)-H Activation.J. Org. Chem.2015,80, 7564.

27. G. Huang*. Mechanism of Rhodium-Catalyzed Cyclopropanation/Cyclization of Allenynes.Org. Lett.2015,17, 1994.

28. G. Huang, Y. Xia*, C. Sun, J. Li, D. Lee*. Theoretical Studies on the Mechanism of the C-H Amination of Silyl Cyclopropenes by Azodicarboxylates.J. Org. Chem.2013,78, 988.

29. G. Huang, K. Xie, D. Lee, Y. Xia*. Reactivity of Alkynyl Metal Carbenoids: DFT Study on the Pt-Catalyzed Cyclopropanation of Propargyl Ester Containing 1,3-Diynes.Org. Lett.2012,14, 3850.

30. G. Huang, B. Cheng, L. Xu, Y. Li*, Y. Xia*. Mechanism of the Transition Metal-Catalyzed Hydroarylation of Bromo-Alkyne Revisited: Hydrogen versus Bromine Migration.Chem. Eur. J.2012,18, 5401.

31. Y. Xia*,G. Huang. Mechanisms of the Au and Pt-Catalyzed Intramolecular Acetylenic Schmidt Reactions: A DFT Study.J. Org. Chem.2010,75, 7842.

五、荣誉和奖励：

天津市高层次人才青年项目（2015）

天津大学-北洋青年骨干教师（2016）

天津大学“教书育人”青年先进工作者（2017）

天津市第十四届青年教师教学竞赛校内选拔赛理科组一等奖（2017）

天津大学2018届本科生毕业设计（论文）优秀指导教师（2018）

天津大学第十二届研究生“我心目中的十佳好导师”（2019）

天津大学沈志康奖教金（2020）

六、讲授主要课程：

有机化学

有机化学实验

计算机实习

多尺度分子计算机模拟

七、主持科研项目：

国家自然科学基金-面上项目（批准号：22073066，2021.1-2024.12）

国家自然科学基金-青年项目（批准号：21503143，2016.1-2018.12）

天津市自然科学基金-青年项目（批准号：16JCQNJC05600，2016.4-2019.3）

天津大学自主创新基金（2017.1-2018.12；2020.1-2020.12）

八、参编教材：

《有机化学（第六版）》赵温涛、郑艳、王光伟、马宁、黄跟平编；高等教育出版社；ISBN：978-7-04-052161-0。

《有机化学（第六版）学习指南》王光伟、聂晶、马宁等编；高等教育出版社；ISBN：978-7-04-054201-1。

九、教改论文：

有机化合物命名原则(2017)的简化及在有机化学教材中的应用，黄跟平、赵温涛*，化学教育，2020，41，20-24.