@Tianjin University
天津大学张淳课题组
张淳教授/博导 天津大学化学系
入选天津大学“北洋学者计划”
办公室:天津大学北洋园校区51教531
e-mail: chunzhang@tju.edu.cn
本课题组常年招收硕士生和博士生,并招聘科研助理和博士后,欢迎联系和访问!
Research Interest:
# Discovery and development of new reaction for bio-active molecule synthesis
# Mechanistic studies of transition metal-catalyzed organic reactions
Education and Working Experience of Chun Zhang:
1. 2017/09 to today: Professor, Department of Chemistry, Tianjin University, Tianjin, China.
2. 2014/04 to 2017/08: Postdoctoral Research Fellow, Professor Matthew S. Sigman group, Department of Chemistry, University of Utah, Salt Lake City, Utah, USA.
3. 2013/08 to 2014/01: Research Assistant, Professor Ning Jiao group, College of Pharmacy, Peking University, Beijing, China.
4. 2008/09 to 2013/07: Ph. D. Candidate, Professor Ning Jiao group, College of Pharmacy, Peking University, Beijing, China.
5. 2004/09 to 2008/07: Undergraduate student, College of Pharmacy, China Pharmaceutical University, Nanjing, China.
Some selected publications:
1. Chun Zhang, Celine B. Santiago, Jennifer M. Crawford, Matthew S. Sigman*, Enantioselective Dehydrogenative Heck Arylations of Tri-substituted Alkenes with Indoles to Construct Quaternary Stereocenters,J. Am. Chem. Soc.2015,137, 15668.
2. Chun Zhang, Celine B. Santiago, Lei Kou, Matthew S. Sigman*, Alkenyl Carbonyl Derivatives in Enantioselective Redox Relay Heck Reactions: Accessing α,β-Unsaturated Systems,J. Am. Chem. Soc.2015,137, 7290.
3. Chun Zhang, Peng feng, Ning Jiao*, Cu-Catalyzed Esterification Reaction via Aerobic Oxygenation and C–C Bond Cleavage: An Approach to α-Ketoesters,J. Am. Chem. Soc.2013,135, 15257.
4. Chun Zhang, Ning Jiao*, Dioxygen activation under ambient conditions: Cu-catalyzed oxidative amidation?diketonization of terminal alkynes leading to α-ketoamides,J. Am. Chem. Soc.2010,132, 28.
5. Chun Zhang, Zejun Xu, Liangren Zhang, Ning Jiao*, Copper-catalyzed aerobic oxidative coupling of aryl acetaldehydes with anilines leading to α-ketoamides,Angew. Chem. Int. Ed.2011,50, 11088.
6. Chun Zhang, Ning Jiao*, Copper-catalyzed aerobic oxidative dehydrogenative coupling of anilines leading to aromatic azo compounds using dioxygen as an oxidant,Angew. Chem. Int. Ed.2010,49, 6174.
7. Zejun Xu,§ Chun Zhang,§ Ning Jiao*, (§ These authors contributed equally to this work) Copper-mediated aerobic oxidative dehydrogenative annulation of aldehydes, amines and molecular oxygen for oxazoles via C-H functionalization and dioxygen activation.Angew. Chem. Int. Ed.2012,51, 11367.
8. Chun Zhang, Brandon Tutkowski, Ryan J. DeLuca, Leo A. Joyce, Olaf Wiest, Matthew S. Sigman*, Palladium-catalyzed enantioselective Heck alkenylation of trisubstituted allylic alkenols: a redox-relay strategy to construct vicinal stereocenters,Chem. Sci.2017,8, 2277.
9. Chun Zhang, Conghui Tang, Ning Jiao*, Recent advances in copper-catalyzed dehydrogenative functionalization via a single electron transfer (SET) process,Chem. Soc. Rev.2012,41, 3464.
10. Chun Zhang, Ning Jiao*, A Cu-catalyzed Practical Approach to α-Ketoesters under Air: an Efficient Aerobic Oxidative Dehydrogenative Coupling of Alcohols and α-Carbonyl Aldehydes,Org. Chem. Frontiers,2014,1, 109.
11. Chun Zhang, Liangren Zhang, Ning Jiao*, Catalyst and additive free procedure to construct benzimidazoles using air as the oxidant under room temperature.Green Chem.2012,14, 3273.
12. Chun Zhang, Xiaolin Zong, Liangren Zhang, Ning Jiao*, Copper-catalyzed aerobic oxidative cross-dehydrogenative coupling (CDC) of amine and α-carbonyl aldehyde: a pratical and efficient method to α-ketoamides with wide substrate scope.Org. Lett.2012,14, 3280.
13. Chun Zhang, Zejun Xu, Tao Shen, Guolin Wu, Liangren Zhang, Ning Jiao*, Mn-mediated aerobic oxidative C-C bond cleavage of aldehydes with dioxygen activation: a simple synthetic approach to formamide.Org. Lett.2012,14, 2362.
14. Chun Zhang, Liangren Zhang, Ning Jiao*, Multiple oxidative dehydrogenative functionalization of aryl acetaldehydes using molecular oxygen as oxidant leading to 2-oxo-acetamidines.Adv. Synth. Catal.2012,354, 1293.
15. Chun Zhang, Zejun Xu, Liangren Zhang, Ning Jiao*, Et3N-catalyzed dehydrogenative oxidation of α-unsubstituted carbonyl compounds with aryl diamine leading to quinoxalines using molecular oxygen as oxidant.Tetrahedron,2012,68, 5258.
16. Chun Zhang, Xiaoyang Wang, Ning Jiao*, Copper-Catalyzed Aerobic Oxidative C–C Bond Cleavage of 1,3-Diaryl-diketones To Synthesize 1,2-Diketones,Synlett,2014,25, 1458.