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黄文华

【来源: | 发布日期:2018-05-17 】
黄文华
出生年月:1966年8月
实验室:51楼543(北洋校区)
手机:13752506293
Email: huangwh@tju.edu.cn

学习和工作经历
2004年7月-现在,天津大学化学系副教授,硕士导师。
2001年8月-2004年7月,Research associate, Department of Chemistry & Chemical Biology and New York Center for Studies on the Origins of Life, Rensselaer Polytechnic Institute, Troy, USA.
1999年9月-2001年7月,Research associate, Department of Chemistry, University of Illinois at Chicago, Chicago, USA.
1995年9月-1998年12月,毕业于中科院上海有机化学研究所并获理学博士学位。
1992年8月-1995年7月,毕业于中科院兰州化学物理研究所并获理学硕士学位。
1989年10月-1992年7月,在湖南省辰溪县耐火材料厂、县经委和县工业局任技术管理干部。
教学活动
现承担生物化学、有机化学和有机化学实验等课程的教学。至2015年12月已指导10名研究生毕业。
研究领域
主要研究方向是元素有机化学,包括有机磷化学和有机硼化学,致力于应用绿色化学和生物化学理念发展新的有机合成方法,应用于碳-碳键偶联、碳-碳双键的形成、小环化合物的合成以及有机小分子催化等方面,现承担国家自然科学基金面上项目一项(No. 21272170,80万)。
发表论文
[1].荣红英,黄文华*。非经典Wittig反应的最新进展。《化学与生物工程》201532(10), doi: 10.3969/j.issn.1672-5425.2015.10.001.[2].Wenhua Huang* and Jie Xu. In situ generation of formaldehyde and triphenylphosphine from (hydroxymethyl)triphenylphosphonium and its application in Wittig olefination. Syn. Commun.2015,45, 1777-1782.[3].Wenhua Huang,* Hong-Ying Rong, and Jie Xu. Cyclica-alkoxyphosphonium salts from (2-(diphenylphosphino)phenyl)methanol and aldehydes and their application in synthesis of vinyl ethers and ketones via Wittig olefination.J. Org. Chem.2015,80, 6628-6638.[4].Wenhua Huang,* Shuang-Hong Zhao and Ning Xu. Aryltriolborates as air- and water-stable bases for Wittig olefination.Synthesis2015, 359-366.[5].Mei-Li Xu and Wenhua Huang*. Syntheses of 9-triptycylisothiocyanate, (10-amino-9-triptycyl)carboxylic acid and their derivatives.Synth. Commun.2014,44, 3435-3440.[6].Wenhua Huang,* Shuang-Hong Zhao and Guang-Ping Dong. Wittig olefination using phosphonium tetraphenylborate in the absence of additional base.Phosphorus, Sulfur, and Silicon and the Related Elements.2014,189, 1802-1810.[7].Mei-Li Xu and Wenhua Huang*. Metal-free carbon-carbon cross-couplings between the ion pairs in sulfonium tetraphenylborates.Tetrahedron Lett.2014, 55, 4230-4232.[8].沙文彬,黄文华。N-(3-甲酰基苯基)甘氨酸衍生物的合成。化学试剂,20133511,963-966.[9].沙文彬,黄文华。硼化合物催化的直接酰胺化反应研究进展。化学与生物工程,2013306,11-16.[10]. Wenhua Huang* and Wen-Bin Sha. Direct amide formation fromN-arylglycine ethyl ester and carboxylic acids catalyzed by phenylboronic acid.J. Chem. Res.2013, 460-463.[11]. Wenhua Huang* and Lai-Ling Wang. One-pot synthesis of cyclopropane derivatives with a controlledcis:transstereoselectivity by Wittig olefination-sulfur ylide cyclopropanation sequence.J. Chem. Res.2013, 380-384.[12]. Wenhua Huang* and Mei-Li Xu. Synthesis of imides and benzoylureas by direct oxidation ofN-methylenes of amides and benzylureas.J. Chem. Res.2013, 77-79.[13]. Wenhua Huang,* Guangping Dong and Zumureti Mijiti. One-pot synthesis of 2,4,5-trisubstituted oxazoles from N-acyl amino acids by a combination of cyclodehydration with N,N0-diisopropylcarbodiimide and Wittig olefination.Tetrahedron2012,68, 977-981.[14]. Hong Yue, Hongmei Zhang, Meiling Wang and Wenhua Huang*. Novel route toN-acyl-N’-formyl aminal.Syn. Commun.2009, 39, 484-491.[15]. Wenhua Huang,* Meiling Wang and Hong Yue. Conversion ofN-acyl amino acids to imides via oxidative decarboxylation induced by Ag+/Cu2+/S2O82- in water.Synthesis2008, 1342-1344.[16]. Wenhua Huang,* Jingyi Li and Lihua Ou. A facile synthesis of isoquinolines,β-carbolines, and 3-deazapurines.Syn. Commun.2007, 37, 2137-2143.[17]. Wenhua Huang* and Li’e Zhang. A facile synthesis of N-formylbenzamides by oxidative decarboxylation of N-aroylglycine induced by Ag+/S2O82-.J. Chem. Res. (S) 2006, 738-739.[18]. Wenhua Huang and James P. Ferris. One-step, regioselective synthesis of up to 50-mers of RNA oligomers by montmorillonite catalysis.J. Am. Chem. Soc.2006,128, 8914-8919[19]. Michael F. Aldersley, James P. Ferris, Wenhua Huang, Prakash C. Joshi & Dmitri Zagorevski. Oligonucleotides from montmorillonite catalysis; Analysis and modeling.Origins of Life and Evolution of the Biosphere2006,36, 289-291.[20]. James P. Ferris, Prakash C. Joshi, Kong-Jiang Wang, Shin Miyakawa and Wenhua Huang. Catalysis in prebiotic chemistry: application to RNA synthesis.Advances in Space Research2004,33, 100-105.[21]. Wenhua Huang and James P. Ferris. Synthesis of 30-40 mers of RNAs from unblocked monomers. A simple approach to the RNA world.Chem. Comm.2003, 1458-1459.[22]. David Crich and Wenhua Huang. Dynamics of alkene radical cation/phosphate anion pair formation from nucleotide C4' radicals. The DNA/RNA paradox revisited.J. Am. Chem. Soc.2001,123, 9239-9245.[23]. Wen-Hua Huang, Yao-Zeng Huang and Li-Xin Dai. Tellurium-zinc exchange between organotelluronium salts and diethylzinc-reaction of the in situ generated mixed diorganozinc with carbonyl compounds.Tetrahedron Lett.1998, 39, 6953-6956.[24]. 黄文华,潘光明。改良法合成两个含硅芳香二酸酐。化学试剂1998,20, 54-55.
学术交流
参加了中国化学会第27-29届学术年会,2015年还参加了第25届国际杂环化学大会,相关工作以口头报告的形式进行了交流。