王建辉 博士（教授）

男， 1969 ， 3 月生，汉族，河北省定州人。

办公室：第七教学楼三层 311 室

Fax: 0086-22-27403475

Phone: 0086-13102013508

E-mail:wjhsq2000@yahoo.com

resent address: Department of Chemistry, College of Science, Tianjin University, Tianjin 300072, P. R. CHINA

教育经历：

.1992吉林大学化学系学士学位

.1995吉林大学化学系硕士学位

.1999吉林大学化学系博士学位

工作经历：

.1995.8吉林大学化学系助教;

.1998.8吉林大学化学系讲师;

.2005.6天津大学化学系教授;

留学经历：

.2001.8 - 2002.6 Department of Chemistry undefinedamp; Biochemistry, Northern Illinois University; Visiting Scholar.

.2002.6 - 2003.10 Department of Chemistry, Southern Methodist University;

Postdoctoral Research Associate.

.2003.11 - 2004.8 Department of Chemistry, University of Florida;

Postdoctoral Research Associate.

.2004.8 - 2005.6 Department of Chemistry, Southern Methodist University;

Postdoctoral Research Associate.

主要研究方向：

一. 纳米合成与组装:探索纳米晶体的新合成途径，研究纳米晶体的形态控制方法，及将纳米

晶体有效地组装成具有一定结构的功能器件。

二. 金属有机化合物在有机化学反应中的应用 :设计合成新颖结构的配体，合成金属有机化合

物，并将其应用于有机化学反应中。近期的工作将集中在两方面：

• 以碳硼烷为基础，设计合成具有新颖结构的金属有机化合物并研究其对烯烃复分解反应的催化作用。

• 设计合成具有新颖结构的金属有机化合物并研究其对氢胺化反应的催化作用。

三. 烯烃聚合催化剂的研究:设计合成具有新颖结构的配体及催化剂， 并研究其对烯烃的聚

合反应的催化作用。

发表文章：

1. Jianhui Wang, Chong Zheng, Gauthami Arikatala, John A. Magure, and Narayan S. Hosmane, “Highly Efficient Synthetic Approach of Half Sandwiched C 2 B 4 -Lanthanacarborane.”Submit for publication.

2. Yunwei Charles Cao, Jianhui Wang ; “One-Pot Synthesis of High-Quality Zinc-Blende CdS Nanocrystals ” J. Am. Chem. Soc.; 2004 ; 126 (44); 14336-14337.

3. Jianhui Wang , Shoujian Li, Chong Zheng, Ang Li, John A. Maguire, and Narayan S. Hosmane “Chemistry of C-Trimethylsilyl-Substituted Heterocarboranes.30. Synthetic and Structural Studies on Oxide Ion Encapsulating Tetralanthanide Tetrahedra Surrounded by “Carbons Apart” C 2 B 4 -Carborane Ligands [Ln(III) = La, Nd, Gd, Tb, Ho and Lu].”Organometallics,2004, 23 (20); 4621-4629 .

4. Jianhui Wang , Chong Zheng, Ang Li, Christina L. Allard, Joanna L. Smith, Gauthami Arikatala, and Narayan S. Hosmane, “ Half-sandwich Halolanthanacarboranes of The “Carbons Ajacent” C 2 B 4 -Carborane Ligand Systems: Important Synthons for New Polyhedral Cage Constructs”.Inorg. Chem. Commun.,2004,7(9), 1078-1081 .

5. Ang Li, Jianhui Wang, Chong Zheng, John A. Maguire, Narayan S. Hosmane, Novel Sandwich Complexes of Terbium and Erbium Metals Derived from Mixed η 5 Open-Pentadienyl and C 2 B 4 Carborane Ligands: A Synthetic and Structural Investigation.Organometallics,2004,23, 3091-3093.

6. Yuetao Zhang, Jianhui Wang , Ying Mu, Zhang Shi, Chunsheng Lu, Yanrong Zhang, Lijun Qiao, Shouhua, Feng, “Synthesis, Structures, and Catalytic Properties of Constrained Geometry Cyclopentadienyl-phenoxytitanium Dichloride.”Organometallics,2003,22, 3877-3883.

7. J ianhui Wang , Chong Zheng, John A. Maguire, and Narayan S. Hosmane. “A New Class of Constrained-Geometry Metallocenes: Synthesis and Crystal Structure of a Carboranyl-Thiol-Appended Half-Sandwich Titanocene and Its Conversion to Halotitanocene. ”Organometallics,2003,22,4839-4841.

8. Jianhui Wang , Shoujian Li, Chong Zheng, Narayan S. Hosmane, John A. Maguire, Herbert W. Roesky, Christopher C. Cummins, Wolfgang Kaim, “An Oxide Ion-Encapsulating Tetraholmium Tetrahedron Stabilized by Complexation with the “Carbons Apart” C 2 B 4 -Carborane Ligands.”Organometallics,2003,22,4390-4392.

9. Jianhui Wang , Shoujian Li, Chong Zheng, John A. Maguire, and Narayan S. Hosmane, “Unsolvated “Carbons Apart” Neodymacarborane Sandwich Stabilized by Bis( h 6 -benzene)potassium Cation: A Unique Dimeric Mixed-Metal Sandwiched Ion-Pair.”Inorg. Chem. Commun.2003,6, 1220-1223.

10. Jianhui Wang , Shoujian Li, Chong Zheng, John A. Maguire, and Narayan S. Hosmane, “Chemistry of C-Trimethylsilyl-Substitued Heterocarboranes. 29. Synthetic and Structural Investigations On Full-Sandwiched Lanthanacarborane Complexes with Two and Three Carbons Apart- Carborane Cages Bonding to Ln (III) Metal [Ln (III) = Nd, Gd, Dy, Ho, Er, Tb and Lu]. ”Organometallics,2003,22, 4334 – 4342.

11. Jianhui Wang , Yinghuai Zhu, Shoujian Li, Chong Zheng, John A. Maguire, and Narayan S. Hosmane, “Group 4 Metallacarboranes of Constrained Geometries Derived from B (cage)- and C (cage) - Silylamido-Substituted Carborane Ligands: A Synthetic and Structural Investigation.”J. Orgmet. Chem.2003,680, 173-181.

12. Jianhui Wang , Shoujian Li, Chong Zheng, John A. Maguire, and Narayan S. Hosmane, “ Metallacarboranes as an Anion and a Cation in a Single Species: A Unique Example for Ion Pairs. ”Inorg. Chem. Commun.2003,6, 549.

13. Jianhui Wang , Shoujian Li, Chong Zheng, John A. Maguire, and Narayan S. Hosmane, “ Synthesis and Crystal Structure of a Carbons-Apart Erbacarborane Sandwich: An Example of Novel, One-Pot, Two-Electron Reductive Cage Opening with Concomitant Metalation of the C 2 B 4 Carborane Ligand . ”Organometallics,2002,21, 5149.

14. Jianhui Wang , Shoujian Li, Chong Zheng, John A. Maguire, and Narayan S. Hosmane, “Novel Lanthanocene Analogues of Carbons Apart Erba- and Dysprosacarboranes: Synthetic and Structural Investigation.”Organometallics,2002,21, 3314.

15. Jianhui Wang , Shoujian Li, Chong Zheng, John A. Maguire, and Narayan S. Hosmane, “Synthesis and Crystal Structure of the First Carbons Apart Diamagnetic Lutetiacarborane Sandwich Complex. ”Inorg. Chem. Commun.,2002,5, 602.

16. Luqman Adams, Sumathy N. Hosmane, Jamey E. Eklund, Jianhui Wang , and Narayan S. Hosmane, “A New Synthetic Route to Boron-10 Enriched Pentaborane (9) from Boric Acid and Its Conversion toanti- 10 B 18 H 22 . ”J. Am. Chem. Soc.,2002,124,7292.

17. Luqman Adams, Susan Tomlinson, Jianhui Wang , Sumathy N. Hosmane, John A. Maguire, and Narayan S. Hosmane, “Novel Approach to Boron-10 Enriched Decaborane (14): an Important Advance in Synthetic Boron Hydride Chemistry. ”Inorg. Chem. Commun.,2002,5, 765.

18. Jianhui Wang , Ying Mu, Weiming Bu, Yuetao Zhang, Guangdi Yang, Juzheng Liu. “Synthesis, Characterization and Catalysis of [ η 5 , η 1 -C 5 H 4 -CHPh-PhO]TiCl 2”Chemical Journal of Chinese Universities (Eng.)2001,17, 115.

19. Jianhui Wang, Ying Mu, Zhan Shi, Suobo Zhang, Shouhua Feng. “Synthesis and Structure of Bis(2, 4-dimethylpentdienyl)gadolinium Chloride.”Chemical Journal of Chinese Universities,2000,21, 892.

20. Fan Zhang, Ying Mu, Jianhui Wang , Zhan Shi, Weiming Bu, Shirong Hu, Yuetao Zhang and Shouhua Feng, “Synthesis and Crystal Structures of Unbridged Bis(4-R-1,2-dipheylcyclopentadienyl) zirconium dichlorides (R = Phenyl, Cyclohexyl), and Catalysis for Olefin Polymerization.”Polyhedron,2000,19, 1941.

21. Weiming Bu, Jianhui Wang, Ling Ye, Ying Mu, Guangdi Yang and Yuguo Fan. “Dichloro{2-[(η 5 -cyclopentadienyl) phenylmethyl] phenolato -O}titanium.”Acta Crystallographica (Section C) Crystal Structure Communications,1999,C55, 728.